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Synthesis 2010(16): 2759-2762
DOI: 10.1055/s-0030-1258144
DOI: 10.1055/s-0030-1258144
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
A Convenient Iron-Catalyzed Method for the Preparation of 1,2-Bis(trimethylsilyl)benzenes
Further Information
Received
4 March 2010
Publication Date:
01 July 2010 (online)
Publication History
Publication Date:
01 July 2010 (online)
Abstract
A convenient iron-catalyzed method for the preparation of 1,2-bis(trimethylsilyl)benzenes is presented. Compared to the current procedures, low temperatures and toxic solvents are avoided, allowing large-scale preparation. Additionally, a variety of substituents are tolerated.
Key words
Grignard reaction - catalysis - iron - silicon - metalation
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