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Synthesis 2010(21): 3724-3730
DOI: 10.1055/s-0030-1258232
DOI: 10.1055/s-0030-1258232
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Efficient General Synthesis of Alkylammonium Diselenophosphinates via Multicomponent One-Pot Reaction of Secondary Phosphines with Elemental Selenium and Amines
Weitere Informationen
Received
5 July 2010
Publikationsdatum:
25. August 2010 (online)
Publikationsverlauf
Publikationsdatum:
25. August 2010 (online)
![](https://www.thieme-connect.de/media/synthesis/201021/lookinside/thumbnails/10.1055-s-0030-1258232-1.jpg)
Abstract
The multicomponent reaction between secondary phosphines, elemental selenium, and primary, secondary, or tertiary amines is accomplished efficiently in ethanol (60 ˚C, 0.5 h) to give the corresponding mono-, di-, or trialkylammonium diselenophosphinates in high yield (up to 97%).
Key words
secondary phosphines - elemental selenium - amines - three-component reaction - diselenophosphinates
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References
All crystallographic data [CCDC 768610 and CCDC 768611] can be obtained free of charge on application to CCDC, 12 Union Road, Cambridge CB2 1EZ, UK [fax: +44(1223)336033, e-mail: deposit@ccdc.cam.ac.uk].