Recyclable Catalysts for Suzuki-Miyaura
Cross-Coupling Reactions at Ambient Temperature Based
on a Simple Merrifield Resin Supported Phenanthroline-Palladium(II)
Complex

Jin Yang; Pinhua Li; Lei Wang

doi:10.1055/s-0030-1258472

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Synthesis 2011(8): 1295-1301
DOI: 10.1055/s-0030-1258472

PAPER

Recyclable Catalysts for Suzuki-Miyaura Cross-Coupling Reactions at Ambient Temperature Based on a Simple Merrifield Resin Supported Phenanthroline-Palladium(II) Complex

Jin Yang^a, Pinhua Li^a, Lei Wang*^a,b
^a Department of Chemistry, Huaibei Normal University, Huaibei, Anhui 235000, P. R. of China
^b State Key Laboratory of Organometallic Chemistry, Shanghai Institute of Organic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. of China
Fax: +86(561)3090518; e-Mail: leiwang@chnu.edu.cn;

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Publikationsverlauf

Received 7 January 2011
Publikationsdatum:
10. März 2011 (online)

Abstract
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Abstract

A novel Merrifield resin immobilized phenanthroline-palladium(II) complex has been developed and was found to be an efficient catalyst for Suzuki-Miyaura cross-coupling reaction between arylboronic acids and a range of aryl halides under mild reaction conditions. The catalyst exhibited both high catalytic activity and stability for Suzuki-Miyaura reaction. Furthermore, the catalyst could be recycled at least 10 times without a significant loss of catalytic activity.

Key words

immobilized catalyst - phenanthroline-palladium(II) complex - Suzuki-Miyaura reaction - recyclability

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