Using Benzotriazole Esters as
a Strategy in the Esterification of Tertiary Alcohols

José Antonio Morales-Serna; Aline Vera; Ehecatl Paleo; Eréndira García-Ríos; Rubén Gaviño; Gustavo García de la Mora; Jorge Cárdenas

doi:10.1055/s-0030-1258970

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Synthesis 2010(24): 4261-4267
DOI: 10.1055/s-0030-1258970

PAPER

Using Benzotriazole Esters as a Strategy in the Esterification of Tertiary Alcohols

José Antonio Morales-Serna^a, Aline Vera^a, Ehecatl Paleo^a, Eréndira García-Ríos^a, Rubén Gaviño^a, Gustavo García de la Mora^b, Jorge Cárdenas*^a
^a Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior, Ciudad Universitaria, Coyoacán 04510, D. F. México City, México
Fax: +52(55)56162217; e-Mail: rjcp@unam.mx;
^b Departamento de Química Orgánica, Facultad de Química, Universidad Nacional Autónoma de México, Circuito Interior, Ciudad Universitaria, Coyoacán 04510, D. F. México City, México

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Publikationsverlauf

Received 13 August 2010
Publikationsdatum:
12. November 2010 (online)

Abstract
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Abstract

Benzotriazole esters formed in situ were found to be efficient intermediates in the esterification of tertiary alcohols using 4-(dimethylamino)pyridine (DMAP) as the base. These mild and basic reaction conditions allow the conversion of various substrates into esters in good yield.

Key words

esterification - hindered alcohols - 1-hydroxybenzotriazole - carbodiimides - hydrotalcites

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