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Synthesis 2011(11): 1678-1690  
DOI: 10.1055/s-0030-1260028
REVIEW
© Georg Thieme Verlag Stuttgart ˙ New York

Inexpensive Copper/Iron-Cocatalyzed Reactions

Yijin Sua, Wei Jiaa, Ning Jiao*a,b
a State Key Laboratory of Natural and Biomimetic Drugs, School of Pharmaceutical Sciences, Peking University, Xue Yuan Road 38, Bejing 100191, P. R. of China
Fax: +86(10)82805297; e-Mail: jiaoning@bjmu.edu.cn;
b State Key Laboratory of Organometallic Chemistry, Chinese Academy of Sciences, Shanghai 200032, P. R. of China
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Publikationsverlauf

Received 10 February 2011
Publikationsdatum:
06. Mai 2011 (online)

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Erratum zu diesem Artikel:

Inexpensive Copper/Iron-Cocatalyzed ReactionsSynthesis 2011; 2011(11): e1-e1
DOI: 10.1055/s-0030-1260050

Abstract

Compared with other transition metals, copper and iron salts are inexpensive and stable to air and moisture. Moreover, iron is considered as an environmentally friendly catalyst. Due to these benign characteristics, both copper and iron catalysis have been extensively­ investigated. More recently, inexpensive copper/iron-cocatalyzed reactions have presented an attractive prospect for organic synthesis. This review presents recent progress in copper/iron-cocatalyzed arylation, alkynylation, C-H functionalization, and conjugate addition reactions.

1 Introduction

2 Arylation Reactions

2.1 C-N Bond Formation

2.2 C-O Bond Formation

2.3 C-S Bond Formation

2.4 Summary

3 Alkynylation Coupling Reactions

3.1 Sonogashira-Type Reactions

3.2 Glaser-Type Coupling

4 C-H Functionalization

5 Conjugate Addition Reactions

6 Conclusion

Key words

copper - iron - cocatalysis

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