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Synthesis 2011(15): 2466-2470  
DOI: 10.1055/s-0030-1260095
PAPER
© Georg Thieme Verlag Stuttgart ˙ New York

Oxidative Addition of 1,3-Dicarbonyl Compounds to Terminal Acetylenes Mediated by Cerium(IV) Ammonium Nitrate

Akhil Sivana, Ani Deepthi*a, Vidya Nandialathb
a Department of Chemistry, Amrita Vishwa Vidyapeetham, Kollam 690525, India
Fax: +91(476)2896178; e-Mail: anideepthi@gmail.com;
b AstraZeneca Pvt. Ltd., Bangalore 560024, India
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Publication History

Received 21 March 2011
Publication Date:
07 July 2011 (online)

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Abstract

Cerium(IV) ammonium nitrate mediated oxidative addition of 1,3-dicarbonyl compounds to terminal acetylenes to yield multisubstituted furan derivatives is reported here. The simplicity of the reaction and the ease of execution are particularly noteworthy.

Key words

cerium(IV) ammonium nitrate - oxidative addition - terminal acetylenes - multisubstituted furans - 1,3-dicarbonyl compounds

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