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Synthesis 2011(20): 3359-3363
DOI: 10.1055/s-0030-1260185
DOI: 10.1055/s-0030-1260185
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New YorkWittig Olefination of Trifluoromethyl Ketones and Allylic Carbonates Mediated by Phosphines
Weitere Informationen
Received
20 June 2011
Publikationsdatum:
24. August 2011 (online)
Publikationsverlauf
Publikationsdatum:
24. August 2011 (online)
Abstract
The Wittig olefination of trifluromethyl ketones and allylic carbonates mediated by tributylphosphine was realized to give corresponding trifluoromethyl dienes in good yields with excellent E-selectivities.
Key words
Wittig - trifluoromethyl ketones - trifluoromethyl olefins - ylides - allylic carbonate
- Supporting Information for this article is available online:
- Supporting Information
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DOI: 10.4125/pd0015th:
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