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Synthesis 2012(1): 137-143
DOI: 10.1055/s-0031-1289621
DOI: 10.1055/s-0031-1289621
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
Novel Strategy for the Bis-Butenolide Synthesis via Ring-Closing Metathesis
Further Information
Received
20 September 2011
Publication Date:
23 November 2011 (online)
Publication History
Publication Date:
23 November 2011 (online)
Abstract
A new synthesis to bis-butenolide derivatives from inexpensive divinylglycol is described, employing a sequential double acylation followed by a double ring-closing metathesis. The selectivity is affected by the choice of catalyst.
Key words
glycerol - pinacol - metathesis - ring closure - lactone
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