An Effective Catalytic α-Phosphoryloxylation
of Ketones with Iodobenzene

Ye Pu; Liumian Gao; Huijun Liu; Jie Yan

doi:10.1055/s-0031-1289630

PAPER

An Effective Catalytic α-Phosphoryloxylation of Ketones with Iodobenzene

Ye Pu^a, Liumian Gao^b, Huijun Liu^a, Jie Yan*^a
^a College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032, P. R. of China
Fax: +86(571)88320238; e-Mail: jieyan87@zjut.edu.cn;
^b Research Institute of Nanjing Chemical Industrial Group, Nanjing 210048, P. R. of China

Abstract

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Abstract

An effective catalytic method for α-phosphoryloxylation of ketones is reported. When ketones were reacted with phosphates in the presence of iodobenzene as the recyclable catalyst and m-chloroperbenzoic acid as the terminal oxidant in acetonitrile at room temperature, the α-phosphoryloxylation of ketones took place easily and the corresponding keto phosphates were obtained in moderate to good yields.

Key words

α-phosphoryloxylation - keto phosphate - hypervalent iodine reagent - catalytic oxidation

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