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Synthesis 2012(3): 393-398
DOI: 10.1055/s-0031-1289667
DOI: 10.1055/s-0031-1289667
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New YorkThe Synthesis of Highly Basic π-Extended Porphyrins by Palladium-Catalyzed Amination
Weitere Informationen
Received
6 October 2011
Publikationsdatum:
04. Januar 2012 (online)
Publikationsverlauf
Publikationsdatum:
04. Januar 2012 (online)

Abstract
Recently synthesized tetrabenzoporphyrins and tetranaphthoporphyrins with extended π-systems and bearing 4-bromophenyl substituents were subjected to palladium-catalyzed amination by primary and secondary amines. The yields of the tetraamino derivatives were markedly dependent on the nature of amine reactant.
Key words
porphyrins - protonations - palladium - aminations - homogeneous catalysis
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- Supporting Information
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