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Synthesis 2012; 44(10): 1521-1525
DOI: 10.1055/s-0031-1290806
DOI: 10.1055/s-0031-1290806
special topic
Copper-Catalyzed Aerobic Oxidative Trifluoromethylation of H-Phosphonates Using Trimethyl(trifluoromethyl)silane
Further Information
Publication History
Received: 16 February 2012
Accepted after revision: 05 March 2012
Publication Date:
11 April 2012 (online)
Abstract
Copper-catalyzed aerobic oxidative trifluoromethylation of readily accessible H-phosphonates was demonstrated for the first time. This method not only provides an alternative method for the facile synthesis of a series of biologically important CF3-phosphonates, but also demonstrates the first example of the efficient construction of a P–CF3 bond via transition-metal catalysis.
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- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
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