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Synthesis 2012; 44(21): 3296-3300
DOI: 10.1055/s-0032-1316776
DOI: 10.1055/s-0032-1316776
paper
Synthesis of the Structure Proposed for Natural Meliloester
Weitere Informationen
Publikationsverlauf
Received: 17. Juli 2012
Accepted after revision: 20. August 2012
Publikationsdatum:
31. August 2012 (online)
![](https://www.thieme-connect.de/media/synthesis/201221/lookinside/thumbnails/10.1055-s-0032-1316776-1.jpg)
Abstract
In an attempt to establish the absolute configuration of meliloester, a natural product isolated from Melilotus alba, the literature structure was synthesized in an enantiopure form. Unexpectedly, the 1H and 13C NMR data was completely incompatible with those reported for the natural product. The corresponding m-hydroxy isomer was also excluded as the structure for the natural product.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
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The structure 1 was previously mentioned in two patents, see: