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Synthesis 2013; 45(3): 370-374
DOI: 10.1055/s-0032-1316838
DOI: 10.1055/s-0032-1316838
paper
A New Method for the Benzylic Oxidation of Alkylarenes Catalyzed by Hypervalent Iodine(III)
Further Information
Publication History
Received: 09 November 2012
Accepted after revision: 04 December 2012
Publication Date:
03 January 2013 (online)
Abstract
A convenient and simple procedure is described for the oxidation of the benzylic C–H moiety of alkylarenes to give the corresponding aryl ketones, using tert-butyl hydroperoxide and m-chloroperoxybenzoic acid in the presence of a catalytic amount of the hypervalent iodine reagent, (diacetoxyiodo)benzene. The reactions typically occur in good yields in 2,2,2-trifluoroethanol as the solvent and at room temperature.
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