Synthesis 2013; 45(4): 527-535
DOI: 10.1055/s-0032-1316847
paper
© Georg Thieme Verlag Stuttgart · New York

A Scalable Synthesis of Chiral Modular Phosphine–Phosphite Ligands

Mehmet Dindaroğlu
,
Anna Falk
,
Hans-Günther Schmalz*
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Publikationsverlauf

Received: 17. Oktober 2012

Accepted after revision: 24. Dezember 2012

Publikationsdatum:
18. Januar 2013 (online)


Abstract

The outstanding usefulness of phenol-derived chiral phosphine–phosphite ligands has recently been shown in a number of transition-metal-catalyzed C–C bond-forming reactions. This is exemplified by the synthesis of five new ligands in an optimized procedure that can be reliably performed on a multigram scale.

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