Convenient Methods to Access Chiral Camphanyl Amine Derivatives by ­Sodium Borohydride Reduction of d-(–)-Camphorquinone Imines

Mariappan Periasamy; Nalluri Sanjeevakumar; Polimera Obula Reddy

doi:10.1055/s-0032-1317012

Synthesis, Inhaltsverzeichnis

Synthesis 2012; 44(20): 3185-3190
DOI: 10.1055/s-0032-1317012

paper

Convenient Methods to Access Chiral Camphanyl Amine Derivatives by Sodium Borohydride Reduction of d-(–)-Camphorquinone Imines

Mariappan Periasamy*

School of Chemistry, University of Hyderabad, Central University PO, Hyderabad 500 046, India, Fax: +91(40)23012460 eMail: mpsc@uohyd.ernet.in

,

Nalluri Sanjeevakumar

School of Chemistry, University of Hyderabad, Central University PO, Hyderabad 500 046, India, Fax: +91(40)23012460 eMail: mpsc@uohyd.ernet.in

,

Polimera Obula Reddy

School of Chemistry, University of Hyderabad, Central University PO, Hyderabad 500 046, India, Fax: +91(40)23012460 eMail: mpsc@uohyd.ernet.in

› Institutsangaben

Abstract

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Abstract

d-(–)-Camphorquinone imines prepared using methanolic ammonia, ethanol amine, exo-(–)-bornylamine, ethylene diamine, propylene diamine, and trans-(R,R)-1,2-diaminocyclohexane, upon reduction using sodium borohydride in methanol, give the corresponding chiral exo amino alcohol and diamine derivatives in good yields (75–95%).

Key words

sodium borohydride - chirality - reduction - diimines - diamines

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Referenzen

References

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Supporting Information

Convenient Methods to Access Chiral Camphanyl Amine Derivatives by ­Sodium Borohydride Reduction of d-(–)-Camphorquinone Imines

Convenient Methods to Access Chiral Camphanyl Amine Derivatives by Sodium Borohydride Reduction of d-(–)-Camphorquinone Imines