Synlett 2012; 23(18): 2631-2634
DOI: 10.1055/s-0032-1317477
letter
© Georg Thieme Verlag Stuttgart · New York

Palladium-Nanoparticle-Catalyzed Matsuda–Heck Reaction in Water

Dipak S. Gaikwad
Department of Chemistry, Shivaji University, Kolhapur 416004, India   Fax: +91(231)2692333   Email: p_dattaprasad@rediffmail.com
,
Dattaprasad M. Pore*
Department of Chemistry, Shivaji University, Kolhapur 416004, India   Fax: +91(231)2692333   Email: p_dattaprasad@rediffmail.com
› Author Affiliations
Further Information

Publication History

Received: 26 July 2012

Accepted after revision: 20 September 2012

Publication Date:
18 October 2012 (online)


Abstract

An eco-friendly, simple method for Matsuda–Heck ­arylation of olefins catalyzed by in situ formed Pd nanoparticles is described in water operable at ambient temperature. A variety of arenediazonium salts were coupled with olefins under ligand-free and aerobic conditions in high yields and stereoselectivity.

Supporting Information