Co(acac)2-Catalyzed Allylic and Benzylic Oxidation by tert-Butyl Hydroperoxide

Xiaoqiang Han; Ziyuan Zhou; Chuan Wan; Yumei Xiao; Zhaohai Qin

doi:10.1055/s-0032-1318172

Synthesis, Table of Contents

Synthesis 2013; 45(5): 615-620
DOI: 10.1055/s-0032-1318172

paper

Co(acac)₂-Catalyzed Allylic and Benzylic Oxidation by tert-Butyl Hydroperoxide

Xiaoqiang Han

Department of Applied Chemistry, China Agricultural University, 2 West Yuanmingyuan Road, Beijing 100193, P. R. of China Fax: +86(10)62731719 Email: xiaoyumei23@126.com Email: qinzhaohai@cau.edu.cn

,

Ziyuan Zhou

Department of Applied Chemistry, China Agricultural University, 2 West Yuanmingyuan Road, Beijing 100193, P. R. of China Fax: +86(10)62731719 Email: xiaoyumei23@126.com Email: qinzhaohai@cau.edu.cn

,

Chuan Wan

Department of Applied Chemistry, China Agricultural University, 2 West Yuanmingyuan Road, Beijing 100193, P. R. of China Fax: +86(10)62731719 Email: xiaoyumei23@126.com Email: qinzhaohai@cau.edu.cn

,

Yumei Xiao*

Department of Applied Chemistry, China Agricultural University, 2 West Yuanmingyuan Road, Beijing 100193, P. R. of China Fax: +86(10)62731719 Email: xiaoyumei23@126.com Email: qinzhaohai@cau.edu.cn

,

Zhaohai Qin*

Department of Applied Chemistry, China Agricultural University, 2 West Yuanmingyuan Road, Beijing 100193, P. R. of China Fax: +86(10)62731719 Email: xiaoyumei23@126.com Email: qinzhaohai@cau.edu.cn

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Abstract

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Abstract

Various allylic and benzylic substrates were oxidized to the corresponding enones, arenealdehydes and aryl ketones in good yields with tert-butyl hydroperoxide in the presence of catalytic amounts of Co(acac)₂ under mild conditions. The reactivity, selectivity, and scope of the reaction were investigated.

Key words

Co(acac)₂ - allylic and benzylic oxidation - tert-butyl hydroperoxide - enones - benzaldehydes - ketones

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References

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