Synthesis of 2-Substituted Benzothiazoles from 1-Iodo-2-nitrobenzenes by a Copper-Catalyzed One-Pot Three-Component Reaction

Jidan Liu; Qingwen Gui; Zhiyong Yang; Ze Tan; Ruqing Guo; Ji-Cheng Shi

doi:10.1055/s-0032-1318304

Synthesis, Inhaltsverzeichnis

Synthesis 2013; 45(7): 943-951
DOI: 10.1055/s-0032-1318304

paper

Synthesis of 2-Substituted Benzothiazoles from 1-Iodo-2-nitrobenzenes by a Copper-Catalyzed One-Pot Three-Component Reaction

Jidan Liu

^aState Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. of China eMail: ztanze@gmail.com

,

Qingwen Gui

^aState Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. of China eMail: ztanze@gmail.com

,

Zhiyong Yang

^aState Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. of China eMail: ztanze@gmail.com

,

Ze Tan*

^aState Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. of China eMail: ztanze@gmail.com

,

Ruqing Guo

^aState Key Laboratory of Chemo/Biosensing and Chemometrics, College of Chemistry and Chemical Engineering, Hunan University, Changsha 410082, P. R. of China eMail: ztanze@gmail.com

,

Ji-Cheng Shi*

^bSchool of Chemistry and Life Science, Guangdong University of Petrochemical Technology, Maoming, Guangdong 525000, P. R. of China eMail: jchshi_mmc@126.com

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Abstract

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Abstract

A novel method was developed for synthesizing 2-substituted 1,3-benzothiazoles through a copper-catalyzed, one-pot, three-component reaction of a 1-iodo-2-nitrobenzene with sodium sulfide and an aldehyde.

Key words

catalysis - copper - multicomponent reactions - heterocycles - cyclizations - sulfur

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Referenzen

References

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