Iodine in Modern Oxidation Catalysis

Peter Finkbeiner; Boris J. Nachtsheim

doi:10.1055/s-0032-1318330

Synthesis, Table of Contents

Synthesis 2013; 45(8): 979-999
DOI: 10.1055/s-0032-1318330

review

Iodine in Modern Oxidation Catalysis

Authors

Peter Finkbeiner

Institut für Organische Chemie, Eberhard Karls Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany Fax: +49(7071)295897 Email: boris.nachtsheim@uni-tuebingen.de
Boris J. Nachtsheim*

Institut für Organische Chemie, Eberhard Karls Universität Tübingen, Auf der Morgenstelle 18, 72076 Tübingen, Germany Fax: +49(7071)295897 Email: boris.nachtsheim@uni-tuebingen.de

Abstract

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Abstract

This review discusses the origins of iodine-mediated oxidation catalysis and gives a comprehensive overview on this young field of research. The focus is set on oxidative C–X bond-forming reactions starting from two unfunctionalized C–H and X–H bonds. In addition, iodine-mediated oxidative domino reactions will be discussed.

1 Introduction

2 Why Iodine?

3 C–N Bond Formations

3.1 Aziridinations

3.2 Oxidative Aminations of Heteroarenes

3.3 Oxidative Aminations of sp³ C–H Bonds

3.4 Oxidative Amidations and Esterifications

4 C–O and C–S Bond Formations

5 C–C Bond Formations

6 Simple Oxidations of Functional Groups

7 Oxidative Domino Reactions

8 Conclusion

Key words

iodine - Umpolung - cross-coupling - oxidation - homogeneous catalysis

Full Text

References

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