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Synthesis 2013; 45(9): 1201-1206
DOI: 10.1055/s-0033-1338293
DOI: 10.1055/s-0033-1338293
paper
PVC-Supported Palladium Nanoparticles: An Efficient Catalyst for Suzuki Cross-Coupling Reactions at Room Temperature
Further Information
Publication History
Received: 08 December 2012
Accepted after revision: 08 March 2013
Publication Date:
21 March 2013 (online)
Abstract
A simple and efficient protocol is described for a Suzuki reaction catalyzed by poly(vinyl chloride)-supported nanoparticles of metallic palladium at room temperature. Aryl iodides, bromides, and chlorides underwent smooth Suzuki reactions in aqueous ethanol, an environmentally friendly solvent, under ligand-free conditions to give good yields of the desired biaryl products. The heterogeneous catalyst could be used up to four times with no detectable metal leaching or loss of catalytic efficiency.
Key words
coupling reactions - supported catalysis - palladium - halides - biaryls - Suzuki reactionsSupporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis. Included are TEM and histogram data for PVC-Pd(0) and 1H and 13C NMR spectra and HRMS spectra for selected compounds.
- Supporting Information
-
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