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Synthesis 2013; 45(9): 1160-1164
DOI: 10.1055/s-0033-1338297
DOI: 10.1055/s-0033-1338297
practical synthetic procedures
Modular Access to 9,9-Spirobifluorenes by Oxidative Coupling Using Molybdenum Pentachloride
Further Information
Publication History
Received: 07 March 2013
Accepted: 11 March 2013
Publication Date:
21 March 2013 (online)
Abstract
The strong oxidizing agent molybdenum pentachloride was used for an efficient direct C–C bond formation of 9,9-diarylfluorenes to the corresponding 9,9-spirobifluorenes. Thus, a versatile method that is compatible with labile groups, such as iodo moieties, was established. By this approach important building blocks for light emitting polymers were synthesized in high yields.
Key words
molybdenum pentachloride - oxidative coupling - spiro compounds - biaryls - C–C bond formationSupporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
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