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Synthesis 2013; 45(19): 2684-2688
DOI: 10.1055/s-0033-1338420
special topic
© Georg Thieme Verlag Stuttgart · New York

Facile Aerobic Photooxidation of Alcohols Using 2-Chloroanthraquinone under Visible Light Irradiation

Yoshiko Shimada
Gifu Pharmaceutical University 1-25-4, Daigaku-nishi, Gifu 501-1196, Japan   Fax: +81(58)2308108   eMail: itoha@gifu-pu.ac.jp
,
Kasumi Hattori
Gifu Pharmaceutical University 1-25-4, Daigaku-nishi, Gifu 501-1196, Japan   Fax: +81(58)2308108   eMail: itoha@gifu-pu.ac.jp
,
Norihiro Tada
Gifu Pharmaceutical University 1-25-4, Daigaku-nishi, Gifu 501-1196, Japan   Fax: +81(58)2308108   eMail: itoha@gifu-pu.ac.jp
,
Tsuyoshi Miura
Gifu Pharmaceutical University 1-25-4, Daigaku-nishi, Gifu 501-1196, Japan   Fax: +81(58)2308108   eMail: itoha@gifu-pu.ac.jp
,
Akichika Itoh*
Gifu Pharmaceutical University 1-25-4, Daigaku-nishi, Gifu 501-1196, Japan   Fax: +81(58)2308108   eMail: itoha@gifu-pu.ac.jp
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Publikationsverlauf

Received: 08. März 2013

Accepted after revision: 20. März 2013

Publikationsdatum:
16. Mai 2013 (online)

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Abstract

A facile photooxidation of alcohols to obtain carboxylic acids and ketones using easily handled 2-chloroanthraquinone as an organocatalyst under visible light irradiation in an air atmosphere is reported. The reaction conditions are mild, such as an air atmosphere and ambient pressure and temperature.

Key words

alcohols - carboxylic acids - 2-chloroanthraquinone - photooxidation - visible light
 

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