A Mild and Efficient Procedure for the N-Functionalization of S-Perfluoroalkylated Aryl Sulfoximines

Abstract

N-Acylated perfluoroalkylated sulfoximines are synthesized easily from the corresponding free NH-sulfoximines on reaction with acid chlorides. This mild procedure is extended to diacid chlorides for the preparation of dimeric N-bridged sulfoximines and to reactions with chloroformates, carbamoyl chlorides, chlorothio­noformates and thiocarbamoyl chlorides as electrophiles.

Key words

fluorinated sulfoximines - acylation - carbamoylation - ureas - N-bridged sulfoximines

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