Synthesis of Novel Octahedral Silicon Compounds; Synthesis of Bis[3-(1-{[aryl(hydroxy)methylene]hydrazinylidene}ethyl)-6-methyl-2-oxo-2H-pyran-4-olato-N,O,O′]silicon(IV)

Sotiria Karamouzi; Anna Maniadaki; Despina A. Nasiopoulou; Elvira Kotali; Antigoni Kotali; Philip A. Harris; James Raftery; John A. Joule

doi:10.1055/s-0033-1338924

Synthesis, Table of Contents

Synthesis 2013; 45(15): 2150-2154
DOI: 10.1055/s-0033-1338924

paper

Synthesis of Novel Octahedral Silicon Compounds; Synthesis of Bis[3-(1-{[aryl(hydroxy)methylene]hydrazinylidene}ethyl)-6-methyl-2-oxo-2H-pyran-4-olato-N,O,O′]silicon(IV)

Sotiria Karamouzi

^aLaboratory of Organic Chemistry, Department of Chemical Engineering, University of Thessaloniki, Thessaloniki 54124, Greece Fax: +30(231)0996253 Email: kotali@eng.auth.gr

,

Anna Maniadaki

^aLaboratory of Organic Chemistry, Department of Chemical Engineering, University of Thessaloniki, Thessaloniki 54124, Greece Fax: +30(231)0996253 Email: kotali@eng.auth.gr

,

Despina A. Nasiopoulou

^aLaboratory of Organic Chemistry, Department of Chemical Engineering, University of Thessaloniki, Thessaloniki 54124, Greece Fax: +30(231)0996253 Email: kotali@eng.auth.gr

,

Elvira Kotali

^aLaboratory of Organic Chemistry, Department of Chemical Engineering, University of Thessaloniki, Thessaloniki 54124, Greece Fax: +30(231)0996253 Email: kotali@eng.auth.gr

,

Antigoni Kotali*

^aLaboratory of Organic Chemistry, Department of Chemical Engineering, University of Thessaloniki, Thessaloniki 54124, Greece Fax: +30(231)0996253 Email: kotali@eng.auth.gr

,

Philip A. Harris

^bGlaxoSmithKline, 1250 South Collegeville Road, P.O. Box 5089, Collegeville, PA 19426-0989, USA

,

James Raftery

^cThe School of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, UK

,

John A. Joule

^cThe School of Chemistry, University of Manchester, Oxford Road, Manchester M13 9PL, UK

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Abstract

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Abstract

The synthesis of new silicon compounds is reported via the cyclization of dehydroacetic acid N-acylhydrazones with silicon tetraacetate. The procedure involves formation of new octahedral hexacoordinated silicon structures.

Key words

octahedral silicon - dehydroacetic acid - N-acylhydrazones - silicon tetraacetate - hypervalent silicon

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References

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