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Synlett 2013; 24(20): 2709-2714
DOI: 10.1055/s-0033-1338983
DOI: 10.1055/s-0033-1338983
letter
A Combination of Copper(0) Powder and Selectfluor Enables Generation of Cationic Copper Species for Mild 1,2-Dicarbonylation of Alkynes
Further Information
Publication History
Received: 08 August 2013
Accepted after revision: 08 September 2013
Publication Date:
05 November 2013 (online)
![](https://www.thieme-connect.de/media/synlett/201320/lookinside/thumbnails/10.1055-s-0033-1338983-1.jpg)
Abstract
A combination of copper powder and Selectfluor permits the generation of cationic copper species that efficiently catalyze 1,2-dicarbonylation of alkynes under mild conditions with water and dioxygen as inexpensive and environmentally benign sources of oxygen.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synlett.
- Supporting Information
-
References and Notes
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For syntheses of 1,2-dicarbonyl compounds by methods other than oxidations of alkynes involving transition metals, see for example:
For selected examples of redox reactions of transition-metal complexes with Selectfluor, see: