Synthesis of Ethyl Arylpropiolates through Palladium-Catalyzed Cross-Coupling­ Reactions of Aryl Iodides with In Situ Generated Lithium Tetrakis(ethoxycarbonylethynyl)indates

Youngchul Park; Dongjin Kang; Woo Hyung Jeon; Taekyu Ryu; Phil Ho Lee

doi:10.1055/s-0033-1339110

Synthesis, Inhaltsverzeichnis

Synthesis 2014; 46(17): 2305-2311
DOI: 10.1055/s-0033-1339110

special topic

Synthesis of Ethyl Arylpropiolates through Palladium-Catalyzed Cross-Coupling Reactions of Aryl Iodides with In Situ Generated Lithium Tetrakis(ethoxycarbonylethynyl)indates

Youngchul Park

Department of Chemistry, Kangwon National University, Chuncheon 200-701, Republic of Korea Fax: +82(33)2595667 eMail: phlee@kangwon.ac.kr

,

Dongjin Kang

Department of Chemistry, Kangwon National University, Chuncheon 200-701, Republic of Korea Fax: +82(33)2595667 eMail: phlee@kangwon.ac.kr

,

Woo Hyung Jeon

Department of Chemistry, Kangwon National University, Chuncheon 200-701, Republic of Korea Fax: +82(33)2595667 eMail: phlee@kangwon.ac.kr

,

Taekyu Ryu

Department of Chemistry, Kangwon National University, Chuncheon 200-701, Republic of Korea Fax: +82(33)2595667 eMail: phlee@kangwon.ac.kr

,

Phil Ho Lee*

Department of Chemistry, Kangwon National University, Chuncheon 200-701, Republic of Korea Fax: +82(33)2595667 eMail: phlee@kangwon.ac.kr

› Institutsangaben

Abstract

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Abstract

An efficient synthetic method to access ethyl arylpropiolates has been developed; it involves a palladium-catalyzed cross-coupling reaction between a wide range of aryl iodides and lithium tetrakis(ethoxycarbonylethynyl)indates (0.35 equiv) generated in situ from indium trichloride and alkynides obtained from ethyl propiolate and n-butyllithium.

Key words

cross-coupling - palladium - indium - lithium tetrakis(ethoxycarbonylethynyl)indate - propiolates - catalysis

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Referenzen

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Zusatzmaterial

Supporting Information

Synthesis of Ethyl Arylpropiolates through Palladium-Catalyzed Cross-Coupling­ Reactions of Aryl Iodides with In Situ Generated Lithium Tetrakis(ethoxycarbonylethynyl)indates

Synthesis of Ethyl Arylpropiolates through Palladium-Catalyzed Cross-Coupling Reactions of Aryl Iodides with In Situ Generated Lithium Tetrakis(ethoxycarbonylethynyl)indates