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Synthesis 2013; 45(16): 2323-2327
DOI: 10.1055/s-0033-1339186
DOI: 10.1055/s-0033-1339186
paper
Copper(I) Iodide Catalyzed Synthesis of Thiophosphates by Coupling of H-Phosphonates with Benzenethiols
Further Information
Publication History
Received: 27 March 2013
Accepted after revision: 15 May 2013
Publication Date:
25 June 2013 (online)
Abstract
A simple, efficient, and new method has been developed for the preparation of thiophosphates from benzenethiols. The method involves copper(I) iodide catalyzed coupling of thiols with H-phosphonates in the presence of triethylamine. The reaction proceeds effectively to afford the corresponding thiophosphates in moderate to good yields via an aerobic dehydrogenative coupling of H-phosphonates with benzenethiols. This method is easy, rapid, and good-yielding for the synthesis of thiophosphates from benzenethiols.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
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