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Synthesis 2013; 45(21): 2959-2965
DOI: 10.1055/s-0033-1339378
DOI: 10.1055/s-0033-1339378
practical synthetic procedures
An Efficient Method for Opening N-Tosylaziridines with Silylated Nucleophiles by Using Polystyrene-Supported 1,5,7-Triazabicyclo[4.4.0]dec-5-ene as a Reusable Organocatalyst
Further Information
Publication History
Received: 14 June 2013
Accepted: 21 June 2013
Publication Date:
12 August 2013 (online)
Abstract
Polystyrene-supported 1,5,7-triazabicyclo[4.4.0]dec-5-ene (PS-TBD) catalyzes the ring opening of N-tosylaziridines with trimethylsilyl cyanide, trimethylsilyl azide, or trimethylsilyl halides to give the corresponding products in high yields. PS-TBD can be easily recovered and reused without significant loss of catalytic activity.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
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