Ligand-Free PdCl₂-Catalyzed Heck Reaction of Arylboronic Acids and Olefins under Reusable TBAB/H₂O Conditions

Abstract

A novel method was developed for Heck reaction of olefins and arylboronic acids using a ligand-free PdCl₂ catalyst to afford­ the coupling products with excellent regio- and stereoselectivity. It is noteworthy that the PdCl₂/CuSO₄/K₂CO₃/TBAB/H₂O system can be recovered and used for three cycles directly.

Key words

ligand-free - reusability - PdCl₂ - Heck reaction - arylboronic acids

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