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Synthesis 2013; 45(22): 3151-3156
DOI: 10.1055/s-0033-1339659
DOI: 10.1055/s-0033-1339659
paper
Solvent- and Ligand-Free Palladium-Catalyzed Amination of Aryl Halides
Further Information
Publication History
Received: 03 June 2013
Accepted after revision: 01 August 2013
Publication Date:
06 September 2013 (online)
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Abstract
An environmentally friendly and economically favorable approach to the formation of C–N bonds is presented. The methodology is particularly interesting in that the reaction is realized under both solvent- and ligand-free conditions and involves the use of a low loading of a palladium catalyst dispersed with the reactants on a suitable solid support. The reaction proceeds rapidly under microwave irradiation.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
-
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For ligand-free Heck reactions, see:
For ligand-free arylation reactions, see:
For ligand-free carbonylation reactions, see:
For ligand-free copper-catalyzed amination reactions, see: