Heterogeneous Transition-Metal-Free Alcohol Oxidation by Graphene Oxide Supported Iodoxybenzoic Acid in Water

Yo-Han Kim; Hyung-Seok Jang; Young-O Kim; So-Dam Ahn; Sewon Yeo; Sang-Myung Lee; Yoon-Sik Lee

doi:10.1055/s-0033-1339673

Synlett, Inhaltsverzeichnis

Synlett 2013; 24(17): 2282-2286
DOI: 10.1055/s-0033-1339673

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Heterogeneous Transition-Metal-Free Alcohol Oxidation by Graphene Oxide Supported Iodoxybenzoic Acid in Water

Yo-Han Kim

^aSchool of Chemical and Biological Engineering, Seoul National University, Gwanak-gu, Seoul 151-744, Republic of Korea eMail: yslee@snu.ac.kr

,

Hyung-Seok Jang

^aSchool of Chemical and Biological Engineering, Seoul National University, Gwanak-gu, Seoul 151-744, Republic of Korea eMail: yslee@snu.ac.kr

,

Young-O Kim

^aSchool of Chemical and Biological Engineering, Seoul National University, Gwanak-gu, Seoul 151-744, Republic of Korea eMail: yslee@snu.ac.kr

,

So-Dam Ahn

^aSchool of Chemical and Biological Engineering, Seoul National University, Gwanak-gu, Seoul 151-744, Republic of Korea eMail: yslee@snu.ac.kr

,

Sewon Yeo

^aSchool of Chemical and Biological Engineering, Seoul National University, Gwanak-gu, Seoul 151-744, Republic of Korea eMail: yslee@snu.ac.kr

,

Sang-Myung Lee*

^bDepartment of Chemical Engineering, Kangwon National University, Chuncheon, Gangwon-do 200-701, Republic of Korea Fax: +82(2)8769625 eMail: sangmyung@kangwon.ac.kr

,

Yoon-Sik Lee*

^aSchool of Chemical and Biological Engineering, Seoul National University, Gwanak-gu, Seoul 151-744, Republic of Korea eMail: yslee@snu.ac.kr

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Abstract

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Abstract

The metal-free oxidation of organic compounds is one of the most demanding reactions in chemical industries. As such, iodoxybenzoic acid (IBX) is an attractive reagent due to its metal-free oxidative activity. To apply IBX for the alcohol oxidation in water, IBX was immobilized on graphene oxide (GO). GO-supported IBX reagent exhibited excellent performance for alcohol oxidation reaction in water with greater than 90% selectivity. It could be reused without significant loss of oxidative activity.

Key words

graphene oxide - iodoxybenzoic acid - alcohol oxidation - water-based system

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Referenzen

References and Notes
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