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Synthesis 2013; 45(21): 2919-2939
DOI: 10.1055/s-0033-1339677
DOI: 10.1055/s-0033-1339677
review
Recent Advances in Transition-Metal-Catalyzed Trifluoromethylation and Related Transformations
Weitere Informationen
Publikationsverlauf
Received: 29. Mai 2013
Accepted after revision: 03. Juli 2013
Publikationsdatum:
02. Oktober 2013 (online)
Dedicated to Professor Huilin Chen on the occasion of his 75th birthday
Abstract
The incorporation of fluorine-containing moieties into organic compounds is of great importance in pharmaceutical, agricultural, and materials science. Transition-metal-mediated perfluoroalkylation reactions have been studied in the past few decades and, owing to need for low-cost and environmentally friendly processes in the industrial and academic communities, the catalytic reaction has attracted much attention and has become a hot research field. Herein, an overview of recent advances on transition-metal-catalyzed trifluoromethylation and difluoromethylation reactions is given. Trifluoromethylthiolation and trifluoromethoxylation reactions are also reviewed.
1 Introduction
1.1 Transition-Metal–Trifluoromethyl Complexes
1.2 Stoichiometric Trifluoromethylation
2 Transition-Metal-Catalyzed Trifluoromethylation
2.1 Copper-Catalyzed Reactions
2.2 Palladium-Catalyzed Reactions
2.3 Other Transition-Metal-Catalyzed Reactions
3 Difluoromethylation
3.1 Direct Difluoromethylation
3.2 Indirect Difluoromethylation
4 Trifluoromethylthiolation
5 Trifluoromethoxylation
6 Conclusion
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