Sulfuric Acid Functionalized Silica-Coated Magnetic Nanoparticles: Preparation and Application in Synthesis of Mono-, Di- and Tri[bis(6-aminopyrimidinyl)methanes]

Ali Reza Karimi; Zeinab Dalirnasab; Marzie Karimi; Fatemeh Bagherian

doi:10.1055/s-0033-1339761

Synthesis, Table of Contents

Synthesis 2013; 45(23): 3300-3304
DOI: 10.1055/s-0033-1339761

paper

Sulfuric Acid Functionalized Silica-Coated Magnetic Nanoparticles: Preparation and Application in Synthesis of Mono-, Di- and Tri[bis(6-aminopyrimidinyl)methanes]

Ali Reza Karimi*

Department of Chemistry, Faculty of Science, Arak University, Arak 38156-8-8349, Iran Fax: +98(861)4173406 Email: a-karimi@araku.ac.ir

,

Zeinab Dalirnasab

Department of Chemistry, Faculty of Science, Arak University, Arak 38156-8-8349, Iran Fax: +98(861)4173406 Email: a-karimi@araku.ac.ir

,

Marzie Karimi

Department of Chemistry, Faculty of Science, Arak University, Arak 38156-8-8349, Iran Fax: +98(861)4173406 Email: a-karimi@araku.ac.ir

,

Fatemeh Bagherian

Department of Chemistry, Faculty of Science, Arak University, Arak 38156-8-8349, Iran Fax: +98(861)4173406 Email: a-karimi@araku.ac.ir

› Author Affiliations

Abstract

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Abstract

Sulfuric acid functionalized silica-coated magnetic nanoparticles (SSA-MNPs) were prepared by a simple method and evaluated as efficient catalysts for the condensation reaction of 6-amino-1,3-dimethyluracil with mono-, di-, or trialdehydes to give the corresponding mono-, di- and tri[bis(6-aminopyrimidinyl)methanes]. The catalyst was simply recycled by the use of an external magnetic field and could be reused five times without significant loss of activity or mass.

Key words

nanostructures - catalysis - condensation - aldehydes - heterocycles - ultrasound

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References

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