Synlett 2013; 24(20): 2671-2674
DOI: 10.1055/s-0033-1339897
letter
© Georg Thieme Verlag Stuttgart · New York

Cryptand-22 as an Efficient Ligand for the Palladium-Catalyzed Mizoroki–Heck Reaction under Air

Barahman Movassagh*
Department of Chemistry, K. N. Toosi University of Technology, P.O. Box 16315-1618, Tehran, Iran   Fax: +98(21)22853650   Email: bmovass1178@yahoo.com
,
Shahriar Yasham
Department of Chemistry, K. N. Toosi University of Technology, P.O. Box 16315-1618, Tehran, Iran   Fax: +98(21)22853650   Email: bmovass1178@yahoo.com
,
Mozhgan Navidi
Department of Chemistry, K. N. Toosi University of Technology, P.O. Box 16315-1618, Tehran, Iran   Fax: +98(21)22853650   Email: bmovass1178@yahoo.com
› Author Affiliations
Further Information

Publication History

Received: 06 August 2013

Accepted after revision: 05 September 2013

Publication Date:
24 October 2013 (online)


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Abstract

An efficient catalytic system for the Mizoroki–Heck cross-coupling reaction was developed based on the air- and heat-stable palladium(II) chloride–cryptand 22 complex. The complex is a highly active catalyst for coupling of aryl iodides, bromides, or chlorides with various olefins.