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Synthesis 2014; 46(02): 212-224
DOI: 10.1055/s-0033-1340286
DOI: 10.1055/s-0033-1340286
paper
Modular Approach to the Synthesis of Polydentate NHC-Ligand Precursors (Benzimidazolium Salts) Containing Axial Chiral 1,1′-Binaphthyl via Pd-Catalyzed N-Arylation of 1,2-Diaminobenzene
Further Information
Publication History
Received: 16 September 2013
Accepted after revision: 28 October 2013
Publication Date:
25 November 2013 (online)
Abstract
A convenient and efficient modular approach to the synthesis of polydentate NHC ligand precursors (benzimidazolium salts) containing axial chiral 1,1′-binaphthyl from 1,2-diaminobenzene and BINOL has been developed. The benzimidazolium salts could be regarded as the potential bidentate, tridentate, and tetradentate NHC ligand precursors.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
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