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Synthesis 2014; 46(06): 809-816
DOI: 10.1055/s-0033-1340619
DOI: 10.1055/s-0033-1340619
paper
Homogeneous Cyclocarbonylation of Alkenols with Iron Pentacarbonyl
Further Information
Publication History
Received: 25 October 2013
Accepted after revision: 19 December 2013
Publication Date:
30 January 2014 (online)
Abstract
We report substantially improved reaction conditions for palladium(II)-catalyzed tandem cyclization–intramolecular oxycarbonylation of (amino)polyols with a terminal double bond, based on utilization of iron pentacarbonyl [Fe(CO)5] as an affordable and safe liquid supply of the carbonyl unit fully replacing gaseous carbon monoxide. Direct comparison with the classical version on a series of previously published substrates illustrates invariably shorter reaction times but comparable yields and selectivity.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
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