Homogeneous Cyclocarbonylation of Alkenols with Iron Pentacarbonyl

Matej Babjak; Martin Markovič; Beáta Kandríková; Tibor Gracza

doi:10.1055/s-0033-1340619

Synthesis, Inhaltsverzeichnis

Synthesis 2014; 46(06): 809-816
DOI: 10.1055/s-0033-1340619

paper

Homogeneous Cyclocarbonylation of Alkenols with Iron Pentacarbonyl

Matej Babjak*

Department of Organic Chemistry, Slovak University of Technology, Radlinského 9, 81237 Bratislava, Slovakia Fax: +421(2)52968560 eMail: matej.babjak@stuba.sk

,

Martin Markovič

Department of Organic Chemistry, Slovak University of Technology, Radlinského 9, 81237 Bratislava, Slovakia Fax: +421(2)52968560 eMail: matej.babjak@stuba.sk

,

Beáta Kandríková

Department of Organic Chemistry, Slovak University of Technology, Radlinského 9, 81237 Bratislava, Slovakia Fax: +421(2)52968560 eMail: matej.babjak@stuba.sk

,

Tibor Gracza

Department of Organic Chemistry, Slovak University of Technology, Radlinského 9, 81237 Bratislava, Slovakia Fax: +421(2)52968560 eMail: matej.babjak@stuba.sk

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Abstract

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Abstract

We report substantially improved reaction conditions for palladium(II)-catalyzed tandem cyclization–intramolecular oxycarbonylation of (amino)polyols with a terminal double bond, based on utilization of iron pentacarbonyl [Fe(CO)₅] as an affordable and safe liquid supply of the carbonyl unit fully replacing gaseous carbon monoxide. Direct comparison with the classical version on a series of previously published substrates illustrates invariably shorter reaction times but comparable yields and selectivity.

Key words

carbonylation - carbonyl complexes - homogeneous catalysis - palladium - iron

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Referenzen

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