Photooxidative Cleavage of Aromatic Alkenes into Aldehydes Using Catalytic Iodine and Molecular Oxygen under Visible Light Irradiation

Akitoshi Fujiya; Atsumasa Kariya; Tomoya Nobuta; Norihiro Tada; Tsuyoshi Miura; Akichika Itoh

doi:10.1055/s-0033-1340735

Synlett, Inhaltsverzeichnis

Synlett 2014; 25(6): 884-888
DOI: 10.1055/s-0033-1340735

letter

Photooxidative Cleavage of Aromatic Alkenes into Aldehydes Using Catalytic Iodine and Molecular Oxygen under Visible Light Irradiation

Akitoshi Fujiya

^aGifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu 501-1196, Japan Fax: +81(58)2308108 eMail: itoha@gifu-pu.ac.jp

,

Atsumasa Kariya

^aGifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu 501-1196, Japan Fax: +81(58)2308108 eMail: itoha@gifu-pu.ac.jp

,

Tomoya Nobuta

^aGifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu 501-1196, Japan Fax: +81(58)2308108 eMail: itoha@gifu-pu.ac.jp

,

Norihiro Tada

^aGifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu 501-1196, Japan Fax: +81(58)2308108 eMail: itoha@gifu-pu.ac.jp

,

Tsuyoshi Miura

^bTokyo University of Pharmacy and Life Sciences, 1432-1 Horinouchi, Hachioji, Tokyo 192-0392, Japan

,

Akichika Itoh*

^aGifu Pharmaceutical University, 1-25-4 Daigaku-nishi, Gifu 501-1196, Japan Fax: +81(58)2308108 eMail: itoha@gifu-pu.ac.jp

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Abstract

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Abstract

We report a method for the photooxidative cleavage of aromatic alkenes to give aldehydes using molecular oxygen as the terminal oxidant, visible light, a catalytic amount of iodine and trifluoroacetic acid.

Key words

alkenes - aerobic - photooxidation - iodine - aldehydes

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Referenzen

References and Notes
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