Palladium-Catalyzed Reactions of Allenes with 2-Iodobenzenesulfonamides: Simple Synthesis of Benzosultams under Green Conditions

M. Nagarjuna Reddy; K. C. Kumara Swamy

doi:10.1055/s-0033-1340821

Synthesis, Table of Contents

Synthesis 2014; 46(08): 1091-1099
DOI: 10.1055/s-0033-1340821

paper

Palladium-Catalyzed Reactions of Allenes with 2-Iodobenzenesulfonamides: Simple Synthesis of Benzosultams under Green Conditions

M. Nagarjuna Reddy

School of Chemistry, University of Hyderabad, Hyderabad 500 046, A. P., India Fax: +91(40)23012460 Email: kckssc@uohyd.ac.in Email: kckssc@uohyd.ernet.in Email: kckssc@yahoo.com

,

K. C. Kumara Swamy*

School of Chemistry, University of Hyderabad, Hyderabad 500 046, A. P., India Fax: +91(40)23012460 Email: kckssc@uohyd.ac.in Email: kckssc@uohyd.ernet.in Email: kckssc@yahoo.com

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Abstract

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Abstract

A palladium-catalyzed reaction for the synthesis of benzosultams from allenes and 2-iodobenzenesulfonamides in poly(ethylene glycol) medium is described. This route is compared with a second method involving an internal Heck reaction of alkene-functionalized 2-iodobenzenesulfonamides. Key products were characterized by single-crystal X-ray crystallography.

Key words

palladium - catalysis - allenes - sulfonamides - green chemistry

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References

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