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Synlett 2014; 25(13): 1847-1850
DOI: 10.1055/s-0034-1378534
DOI: 10.1055/s-0034-1378534
letter
Hyperbranched Polyamines: Tunable Catalysts for the Henry Reaction
Further Information
Publication History
Received: 12 April 2014
Accepted after revision: 27 May 2014
Publication Date:
09 July 2014 (online)
Abstract
Hyperbranched polyethylenimine derivatives were successfully employed as catalyst in the Henry reaction. The nitroalcohol products were obtained in excellent yields within short reaction times. A one-pot synthesis of β-nitrostyrenes was developed by using ZnCl2 along with hyperbranched polyethylenimine derivatives.
Key words
Henry reaction - diastereoselectivity - polyamine - homogeneous catalysis - β-nitrostyreneSupporting Information
- for this article is available online at http://www.thieme-connect.com/products/ejournals/journal/ 10.1055/s-00000083.
- Supporting Information
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