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Synthesis 2014; 46(19): 2579-2584
DOI: 10.1055/s-0034-1378550
DOI: 10.1055/s-0034-1378550
paper
Electrochemical Synthesis of Potassium Aryltrifluoroborates
Weitere Informationen
Publikationsverlauf
Received: 31. Mai 2014
Accepted: 09. Juli 2014
Publikationsdatum:
07. August 2014 (online)
Abstract
Potassium aryltrifluoroborates were efficiently synthesized using an electrochemical method for the reduction of the corresponding aryl bromides in the presence of triisopropyl borate. The products were obtained in short reaction times with moderate to good yields at room temperature. The methodology is simple, fast and efficient, and is synthetically useful once it was applied in the synthesis of a fragment of combretastatin D2, a natural product with antiproliferative activity.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/products/ejournals/journal/ 10.1055/s-00000084. Included are 1H, 13C, 19F and 11B NMR spectra for all synthesized compounds.
- Supporting Information
-
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