Synthesis 2015; 47(18): 2799-2804
DOI: 10.1055/s-0034-1378782
special topic
© Georg Thieme Verlag Stuttgart · New York

CuAAC Synthesis of Tetragonal Building Blocks Decorated with Nucleobases

Lidia Pop
a   Babeş-Bolyai University, Supramolecular Organic and Organometallic Chemistry Center (SOOMCC), Cluj-Napoca, 11 Arany Janos Str., 400028 Cluj-Napoca, Romania
,
Mirabela Ligia Golban
a   Babeş-Bolyai University, Supramolecular Organic and Organometallic Chemistry Center (SOOMCC), Cluj-Napoca, 11 Arany Janos Str., 400028 Cluj-Napoca, Romania
,
Niculina D. Hădade
a   Babeş-Bolyai University, Supramolecular Organic and Organometallic Chemistry Center (SOOMCC), Cluj-Napoca, 11 Arany Janos Str., 400028 Cluj-Napoca, Romania
,
Crina Socaci
a   Babeş-Bolyai University, Supramolecular Organic and Organometallic Chemistry Center (SOOMCC), Cluj-Napoca, 11 Arany Janos Str., 400028 Cluj-Napoca, Romania
b   National Institute of Research and Development for Isotopic and Molecular Technologies (INCDTIM), Cluj-Napoca, 65-103 Donath Str., 400293 Cluj-Napoca, Romania   eMail: igrosu@chem.ubbcluj.ro
,
Ion Grosu*
a   Babeş-Bolyai University, Supramolecular Organic and Organometallic Chemistry Center (SOOMCC), Cluj-Napoca, 11 Arany Janos Str., 400028 Cluj-Napoca, Romania
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Weitere Informationen

Publikationsverlauf

Received: 03. Mai 2015

Accepted after revision: 20. Juni 2015

Publikationsdatum:
04. August 2015 (online)


Abstract

The CuAAC synthesis and the characterization of new rigid nucleobase-decorated tetrapodands exhibiting 1,3,5,7-tetraphenyladamantane and 9,9′-spirobifluorene central units are reported. 1,3,5,7-Tetraphenyladamantane and 3,3′,6,6′-tetrasubstituted 9,9′-spirobifluorene derivatives are tetrahedral building blocks, while the derivatives of 2,2′,7,7′-tetrasubstituted 9,9′-spirobifluorene can lead to 2D architectures.

Supporting Information

 
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