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Synthesis 2015; 47(01): 129-133
DOI: 10.1055/s-0034-1379029
DOI: 10.1055/s-0034-1379029
paper
Synthesis of tert-Butyl 1,3-Diaryl-3-oxopropylcarbamates by a Regiocontrolled Reduction of Ketoaziridines
Weitere Informationen
Publikationsverlauf
Received: 03. Juli 2014
Accepted after revision: 06. August 2014
Publikationsdatum:
17. September 2014 (online)
Abstract
A new, convenient approach for the reductive ring opening of N-H ketoaziridines is described. Treatment of N-H ketoaziridines with di-tert-butyl dicarbonate [(Boc)2O] in the presence of sodium iodide and nickel(II) chloride results in the corresponding tert-butyl 1,3-diaryl-3-oxopropylcarbamates by a regiocontrolled reaction. The structure of the regioisomeric product was confirmed by X-ray crystal structure analysis.
Supporting Information
- for this article is available online at http://www.thieme-connect.com/products/ejournals/journal/ 10.1055/s-00000084.
- Supporting Information
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