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Synthesis 2015; 47(01): 108-112
DOI: 10.1055/s-0034-1379104
DOI: 10.1055/s-0034-1379104
paper
Palladium-Catalyzed Alcoholysis of 3-Iodopropynamides: Selective Synthesis of Carbamoylacetates
Further Information
Publication History
Received: 10 July 2014
Accepted after revision: 15 August 2014
Publication Date:
25 September 2014 (online)
Abstract
A novel and selective method for the synthesis of carbamoylacetates via the alcoholysis of 3-iodopropynamides has been developed. 3-Iodopropynamides react with alcohols in the presence of palladium(II) acetate and DABCO to afford the corresponding carbamoylacetates in moderate to good yields.
Key words
palladium - 1,4-diazabicyclo[2.2.2]octane - alcoholysis - 3-iodopropynamides - carbamoylacetatesSupporting Information
- for this article is available online at http://www.thieme-connect.com/products/ejournals/journal/ 10.1055/s-00000084.
- Supporting Information
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