The Synthesis of Medium-Chain-Length β-Hydroxy Esters via the Reformatsky Reaction

Miloslav Sailer; Krystyn I. Dubicki; John L. Sorensen

doi:10.1055/s-0034-1379479

Synthesis, Inhaltsverzeichnis

Synthesis 2015; 47(01): 79-82
DOI: 10.1055/s-0034-1379479

paper

The Synthesis of Medium-Chain-Length β-Hydroxy Esters via the Reformatsky Reaction

Autor*innen

Miloslav Sailer

Department of Chemistry, University of Manitoba, Winnipeg, MB, R3T 2N2, Canada Fax: +1(204)4747608 eMail: John.Sorensen@umanitoba.ca
Krystyn I. Dubicki

Department of Chemistry, University of Manitoba, Winnipeg, MB, R3T 2N2, Canada Fax: +1(204)4747608 eMail: John.Sorensen@umanitoba.ca
John L. Sorensen*

Department of Chemistry, University of Manitoba, Winnipeg, MB, R3T 2N2, Canada Fax: +1(204)4747608 eMail: John.Sorensen@umanitoba.ca

Abstract

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Abstract

The synthesis of medium-chain-length β-hydroxy esters in good yield via the Reformatsky reaction is described. This work will be used as the basis for further investigation of hydroxyalkanoate polymers as potential feedstock for biofuel production.

Key words

Reformatsky reaction - biosynthesis - polyhydroxyalkanoate - biofuel - 3-hydroxy esters - Pseudomonas putida

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Referenzen

References
1 Issariyakul T, Dalai AK. Renew. Sust. Energ. Rev. 2014; 31: 446
2 Sharman KP, Fu J, Cicek N, Sparling R, Levin BD. Can. J. Microbiol. 2012; 58: 982
3 Yates MR, Barlow CY. Resour. Conserv. Recycl. 2013; 78: 54

4a Ocampo R, Dolbier RW. Jr. Tetrahedron 2004; 60: 9325
4b Fürstner A. Synthesis 1989; 571

5 Orsini F, Sello G. Curr. Org. Synth. 2004; 1: 111

6a Marcotte S, Pannecoucke X, Feasson C, Quirion J. J. Org. Chem. 1999; 64: 8461
6b Sorochinsky A, Voloshin N, Markovsky A, Belik M, Yasuda N, Uekusa H, Ono T, Berbasov OD, Soloshonok VA. J. Org. Chem. 2003; 68: 7448

7 Chattopadhyay A, Salaskar A. Synthesis 2000; 561
8 Girgis JM, Liang KJ, Du Z, Slade J, Prasad K. Org. Process Res. Dev. 2009; 13: 1094
9 Loh G, Tanigawara R, Shaik MS, Sa-ei K, Wong L, Sharratt NP. Org. Process Res. Dev. 2012; 16: 958

Zusatzmaterial

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