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Synthesis 2015; 47(14): 2038-2054
DOI: 10.1055/s-0034-1380535
DOI: 10.1055/s-0034-1380535
paper
(η6-[7]Heliphene)tricarbonylchromium via an Optimized Preparation of [7]Heliphene
Further Information
Publication History
Received: 11 February 2015
Accepted: 16 March 2015
Publication Date:
23 April 2015 (online)
![](https://www.thieme-connect.de/media/synthesis/201514/lookinside/thumbnails/ss-2015-m0104-op_10-1055_s-0034-1380535-1.jpg)
Abstract
Optimized procedures to [7]heliphene are described that allowed the synthesis of (η6-[7]heliphene)tricarbonylchromium and a preliminary exploration of its chemical behavior. DFT calculations provide structural and energetic information on this complex and its haptomeric isomers. Attempts to prepare the corresponding ([7]heliphene)chromium sandwich failed so far, but DFT evidence is presented to indicate that the target should be accessible.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0034-1380535.
- Supporting Information
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For a review of the parent phenylenes, see:
For subsequent work, see:
For a review, see:
For haptotropism in phenylene complexes, see: CpCo complexes
Cr(CO)3 complexes
See, for example:
See also:
See also:
See, for example:
The topic of the aromaticity of (benzene)tricarbonylchromium has enjoyed a lively debate:
See, for example: Cr(CO)3 complexes
Helicenes
For selected reviews, see:
The phenylenes are deformed readily:
See, for example: Palladium
Tungsten:
Rhodium:
Rhenium: