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Synthesis 2015; 47(21): 3286-3291
DOI: 10.1055/s-0035-1560476
DOI: 10.1055/s-0035-1560476
feature
Base-Free Palladium-Catalyzed Cross-Coupling of Arylsulfonium Salts with Sodium Tetraarylborates
Weitere Informationen
Publikationsverlauf
Received: 12. Juli 2015
Accepted after revision: 24. August 2015
Publikationsdatum:
08. September 2015 (online)
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Abstract
Palladium-catalyzed cross-coupling reactions of arylsulfonium salts with sodium tetraarylborates were found to proceed smoothly without recourse to an additional base, providing a new, reliable route to biaryls from organosulfur compounds.
Key words
C–S cleavage - C–C bond formation - cross-coupling - sulfonium salts - sodium tetraarylborates - palladiumSupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1560476.
- Supporting Information
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For examples of base-free reactions with other organoboron reagents, see:
For reviews on the cross-coupling of organosulfur compounds, see:
For pioneering work on the cross-coupling of organic sulfides, see:
For our work on the cross-coupling of aryl sulfides, see: