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Synthesis 2016; 48(03): 429-436
DOI: 10.1055/s-0035-1560834
DOI: 10.1055/s-0035-1560834
paper
Oxidation of Aryl Sulfides to Sulfones with Alumina-Supported Ruthenium Catalyst in Dimethyl Carbonate–Water Media
Further Information
Publication History
Received: 02 August 2015
Accepted after revision: 06 October 2015
Publication Date:
03 December 2015 (online)
Abstract
A new procedure for the oxidation of sulfides to sulfones utilizing heterogeneous ruthenium reagent has been developed. A small amount of ruthenium trichloride (RuCl3) supported on alumina and excess sodium metaperiodate (NaIO4) was used to produce the ruthenium oxidizing catalyst in the reaction mixture. Sodium metaperiodate oxidized the pre-catalyst RuCl3 to RuO4 and also maintained a constant supply of RuO4 by oxidizing lower valent ruthenium ions during the course of the reaction. An environmentally friendly solvent mixture of dimethyl carbonate (DMC) and water was employed. A wide variety of aromatic sulfides were oxidized to sulfones in good to excellent yields by utilizing this procedure.
Supporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-1560834.
- Supporting Information
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