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Synthesis 2016; 48(06): 804-815
DOI: 10.1055/s-0035-1561321
DOI: 10.1055/s-0035-1561321
short review
Palladium-Catalyzed Olefination of Aryl C–H Bonds by Using Directing Scaffolds
Further Information
Publication History
Received: 03 November 2015
Accepted after revision: 15 December 2015
Publication Date:
26 January 2016 (online)
Abstract
Site selective C–H bond activation/C–C bond formation is an ideal target for organic chemists owing to the ubiquitous nature of C–H bonds in natural products. A particular aryl C–H bond can be predictably activated by a directing group. However, the majority of strong and weak coordinating directing groups have been implemented for ortho-C–H bond activation/C-alkenylation. More recently, meta-C–H functionalization has been promoted by fine-tuning directing templates. In this short review, we have summarized recent progress in palladium-catalyzed directing group/template-assisted ortho/meta-C–H olefination.
1 Introduction
2 Proximal C–H Olefination
3 Distal C–H Olefination
4 Conclusions
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