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Synthesis 2016; 48(10): 1561-1567
DOI: 10.1055/s-0035-1561394
DOI: 10.1055/s-0035-1561394
paper
Stereoselective Total Synthesis of Cryptomoscatone F1
Weitere Informationen
Publikationsverlauf
Received: 23. Dezember 2015
Accepted after revision: 12. Februar 2016
Publikationsdatum:
07. März 2016 (online)
![](https://www.thieme-connect.de/media/synthesis/201610/lookinside/thumbnails/ss-2015-z0736-op_10-1055_s-0035-1561394-1.jpg)
Abstract
A concise stereoselective total synthesis of cryptomoscatone F1 has been accomplished by utilization of asymmetric acetate aldol reaction, Brown’s asymmetric allylation, and olefin cross-metathesis as key transformations.
Key words
cryptomoscatone F1 - acetate aldol reaction - Brown’s asymmetric allylation - olefin cross-metathesisSupporting Information
- Supporting information for this article is available online at http://dx.doi.org/10.1055/s-0035-16561394.
- Supporting Information
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For our contributions on lactone-containing molecules, see:
For the synthesis of (4S)-3-acetyl-4-benzylthiazolidine-2-thione, see:
Procedures for the syn-aldol reaction were adapted from: