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Synthesis 2016; 48(18): 2969-2980
DOI: 10.1055/s-0035-1562439
DOI: 10.1055/s-0035-1562439
short review
Recent Advances in Transition-Metal-Catalyzed Iodination of Arenes
Further Information
Publication History
Received: 22 April 2016
Accepted: 12 May 2016
Publication Date:
20 June 2016 (online)
Abstract
Aryl and heteroaryl iodides are ubiquitous synthetic building blocks used in a wide range of transformations including coupling and radical reactions. These compounds are also found as components of many pharmaceutically active agents and used for medical imaging. Due to their importance, a range of transition-metal-catalyzed methods have recently been developed for their efficient preparation. This short review gives an overview of the progress made and highlights the benefits of transition-metal-catalyzed methods over more traditional approaches.
1 Introduction
2 Halogen-Exchange Reactions
3 Copper-Catalyzed Iodination Using Boronic Acids and Esters
4 Electrophilic Aromatic Substitution
4.1 Gold-Catalyzed Reactions
4.2 Indium-, Iron-, and Silver-Catalyzed Reactions
5 Iodination via C–H Activation
5.1 Palladium-Catalyzed Reactions
5.2 Rhodium-, Ruthenium-, and Cobalt-Catalyzed Reactions
5.3 Copper-Catalyzed Reactions
6 Iododecarboxylation
7 Conclusions
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Modified versions of the Sandmeyer reaction have been developed that can be done under relatively mild conditions. For example, see:
For example, see:
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